• Studies on the effect of extraction of isophorone diisocyanate-based segmented polyurethanes

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/101/06/0455-0465

    • Keywords

       

      Polyurethane; isophorone diisocyanate; extraction; degradation; allophanate linkage

    • Abstract

       

      Linear segmented polyurethane was synthesised, using isophorone diisocyanate (IPDI), poly(tetramethylene oxide) glycol (PTMG) and 1,4 butanediol, for use in biomedical applications. The chemical stability of this polyurethane in hot methanol during Soxhlet extraction was studied by viscosity measurements, thermal studies, mechanical tests, ultraviolet and infrared spectral studies, and gel permeation chromatography. Hot methanol degrades the polymer at the allophanate linkages, while extracting low molecular weight polyurethane fractions. More urea linkages are formed in the extracted polymer.

    • Author Affiliations

       

      N Shunmuga Kumar1 M Jayabalan1

      1. Sree Chitra Tirunal Institute for Medical Sciences and Technology, Division for Technical Evaluation of Biomaterials, BMT Wing, Trivandrum - 695 012, India
    • Dates

       
  • Journal of Chemical Sciences | News

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