• Some neutral three-coordinate complexes of mercury(II) halides and pseudohalides with N-methylnicotinamide

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      https://www.ias.ac.in/article/fulltext/jcsc/101/06/0449-0454

    • Keywords

       

      Mercury(II) halide and pseudohalide complexes; N-methylnicotinamide complexes; three-coordinate mercury(II) complexes

    • Abstract

       

      Coordination compounds of mercury(II) chloride, bromide, cyanide and thiocyanate with N-methylnicotinamide, a potentially bidentate ligand, have been prepared. The complexesisolated have 1∶1 (metal:ligand)stoichiometry. Molecular weight measurements in molten camphor indicate that the mercury (II) chloride and bromide complexes are monomeric. Based on conductance values, molecular weight determinations and infrared spectral data, it is inferred that in the solid state in all these complexes the metal ion has a coordination number three and is bonded to the N-methylnicotinamide via its pyridine ring nitrogen, and is terminally bonded to the halogen/pseudohalogens.

    • Author Affiliations

       

      I S Ahuja1 C L Yadava2 Shailendra Tripathi1

      1. Chemistry Department, Banaras Hindu University, Varanasi - 221 005, India
      2. Chemistry Department, Kamla Nehru Institute of Physical and Social Sciences, Sultanpur - 228 118, India
    • Dates

       
  • Journal of Chemical Sciences | News

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