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    • Complexation behaviour of benzilmono(Iepidyl)hydrazone (BLH) toward bivalent metal ions: A potentiometric study

      B S Garg M R Choudhury R Dixit

      Inorganic and Analytical Volume 101 Issue 5 October 1989 pp 361-369

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/101/05/0361-0369

    • Keywords

       

      Stability constants; thermodynamic parameters; benzilmono(lepidyl)hydrazone; bivalent ions

    • Abstract

       

      Potentiometric investigations on metal complexes of various bivalent metal ions, viz. UO2(II), Cu(II), Ni(II), Co(II), Cd(II), Pb(II), Zn(II) and Mn(II) with benzilmonol(lepidy!)hydrazone (BLH) have been carried out at different ionic strengths and at different temperatures in order to determine stability constants of the complexes. Thermodynamic parameters ΔC, ΔH and ΔS have also been evaluated from temperature coefficient data. The effect of varying the dielectric constant of the medium on the stability constants of complexes has also been investigated at 30±0.5°C and μ = 0.1MNaCl. Thermodynamic stability constants and thermodynamic stabilization energies for the first transition metals have also been discussed.

    • Author Affiliations

       

      B S Garg1 M R Choudhury1 R Dixit1

      1. Department of Chemistry, University of Delhi, Delhi - 110007, India

    • Dates

       
      Published
      October 1989
      Manuscript received
      3 March 1989
      Manuscript revised
      9 June 1989

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