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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/101/04/0327-0334

    • Keywords

       

      Clathrates; azo dye; crystallography; disorder; twinning; solid state reaction

    • Abstract

       

      The compound 3-hydroxy-6-(4′-nitro)phenylazopyridine (1) was observed to incorporate several organic solvents of crystallisation, forming stable clathrates. These clathrates decompose upon heating and the host material is chemically transformed. Single crystal X-ray diffraction studies on the ethanol clathrate lead to a reasonable model for the host structure. But the guest molecules are severely disordered. Alternatively, the compound forms twinned crystals. The chemically closely related compound2 does not form clathrates.

    • Author Affiliations

       

      P Ramachandra1 T Siva Rama Krishna1 Gautam R Desiraju1

      1. School of Chemistry, University of Hyderabad, Hyderabad - 500134, India
    • Dates

       
  • Journal of Chemical Sciences | News

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