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    • Polarographic analysis of the reduction waves of Pt(II)-SATSC complex

      R Palaniappan Agnes Paul

      Inorganic and Analytical Volume 101 Issue 2 April 1989 pp 115-120

    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/101/02/0115-0120

    • Keywords

       

      Polarographic analysis; Pt(II)-salicylaldehyde thiosemicarbazone system; catalytic hydrogen wave

    • Abstract

       

      A polarographic study of the Pt(II)-salicylaldehyde thiosemicarbazone complex in sodium perchlorate as supporting electrolyte is described. In addition to the reduction wave of the complex, a catalytic hydrogen wave is also recorded. The characteristics of this catalytic hydrogen wave are studied under different experimental conditions such as varying acid/complex/supporting electrolyte/surfactant concentrations and also with mercury droptime. Based on these, a probable mechanism for the electrode process has been postulated.

    • Author Affiliations

       

      R Palaniappan1 Agnes Paul1

      1. Department of Analytical Chemistry, University of Madras, Guindy Campus, Madras - 600025, India

    • Dates

       
      Published
      April 1989
      Manuscript received
      23 May 1988
      Manuscript revised
      5 November 1988

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