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    • Microscopic expression for time-dependent solvation energy of ions and dipoles in dense polar liquids

      Amalendu Chandra Biman Bagchi

      Rapid Communications Volume 101 Issue 1 February 1989 pp 83-88

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      https://www.ias.ac.in/article/fulltext/jcsc/101/01/0083-0088

    • Abstract

       

      Microscopic expressions for the time dependence of solvation energies of newly created ions and dipoles in a dense dipolar liquid are presented. It is shown that: (i) the dynamics of solvation of an ion differ considerably from that of a dipole, especially that the long wavelength (k=0) component of solvent response is totally absent for dipoles, and (ii) the translational modes of the solvent molecules lead to a breakdown of Onsager’s conjecture on the distance dependence of solvent polarization relaxation.

    • Author Affiliations

       

      Amalendu Chandra1 Biman Bagchi1

      1. Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore - 560012, India

    • Dates

       
      Published
      February 1989
      Manuscript received
      12 January 1989

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