• Quinone studies. Part III. Metal ion-catalysed oxidation of halophenols and halonaphthols by peroxidisulphate

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      https://www.ias.ac.in/article/fulltext/jcsc/101/01/0025-0032

    • Keywords

       

      Metal ion-catalysed oxidation; halophenols; halonaphthols; peroxidisulphate; halo-1, 4-quinones

    • Abstract

       

      Oxidation of representative halophenols and halonaphthols by peroxidisulphate has been examined. The influence of metallic ions, viz. Cu2+, Fe3+, Ag+, on the above reaction has been studied. Cu2+ ion-catalyzed oxidation gives halo-1, 4-quinones in excellent yield. Potassium bis(biureto)cuprate(III) complex also oxidises halophenols to halo-1, 4-quinones.

    • Author Affiliations

       

      P Thirumalai Perumal1 M Vivekananda Bhatt1

      1. Department of Organic Chemistry, Indian Institute of Science, Bangalore - 560012, India
    • Dates

       
  • Journal of Chemical Sciences | News

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