A series of complexes of Cu(I) and Ag(I) with 4,5-diphenylimidazole-2-thione (L2H) have been isolated and characterized by chemical analyses, electrical conductance, magnetic and IR spectral data. These studies revealed that the ligand coordinates with the central metal ion in one of the following ways: (1) neutral monodentate, (2) anionic bidentate or (3) S-coordinate with an additional M-N interaction.
Volume 134, 2022
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