Different molar reactions of Fe(OPr1)3, and FeCl3 with benzothiazolines having an NSH donor system. derived by the condensation ofo-aminothiophenol with heterocyclic aldehydes. viz. pyridine-2-aldehyde. furfuraldehyde and thiophene-2-aldehyde. lead to the formation of [Fe.Pr1(NS)2]2, [Fc(NS)3] and [Fe(NS)2Cl¦ type of complexes. The resulting derivatives have been characterized by elemental analysis, conductivity measurements, molecular weight determinations and magnetic studies. IR, electronic, Mössbauer and ESR spectral data have been used to deduce the structures of the resulting derivatives.
Volume 132, 2020
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