• Dynamics of polar solvation: Route to single exponential relaxation via translational diffusion

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    • Keywords


      Polar solvation; single exponential relaxation; translational diffusion; time-dependent solvation energy

    • Abstract


      A microscopic theoretical calculation of time-dependent solvation energy shows that the solvation of an ion or a dipole is dominated by a single relaxation time if the translational contribution to relaxation is significant.

    • Author Affiliations


      Biman Bagchi1 Amalendu Chandra1

      1. Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore - 560 012, India
    • Dates

  • Journal of Chemical Sciences | News

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