• One-pot, three-component, sequential Michael-Michael-ring-closure reactions. Annulation of meta-dicarboxylated aromatic rings. Total synthesis of juncunol

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    • Keywords


      Sequential Michael-Michael-ring-closure reactions; one-pot reactions; benzannulations; juncunol

    • Abstract


      The preparative value of one-pot, multicomponent, sequential Michael-Michael-ring-closure reactions followed by aromatization is illustrated in two ways: (1) by a multi-gram example, and (2) by a total synthesis of juncunol, an unusual vinyldihydrophenanthrene.

    • Author Affiliations


      Gary H Posner1 Karen A Canella1 Ernest F Silversmith1

      1. Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland - 21218, USA
    • Dates

  • Journal of Chemical Sciences | News

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