• Synthesis and characterization of Ru(III), Rh(III), Pt(IV) and Ir(III) thiosemicarbazone complexes

    • Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/100/01/0021-0026

    • Keywords

       

      2-Furfural thiosemicarbazone; deprotonated ligand; magnetic moment; reflectance spectra; effective positive charge; infrared spectra

    • Abstract

       

      Ru(III), Rh(III), Pt(IV) and Ir(III) complexes of 2-furfural thiosemicarbazone as ligand have been synthesised. These complexes have the composition [M(ligand)2X2]X (M = Ru(III) Rh(III) and Ir(III) X = Cl and Br) and [Pt(ligand)2 X2] X2 (X = Cl, Br and 1/2SO4). The deprotonated ligand forms the complexes of the formulae M(ligand-H)3 and Pt(ligand-H)3Cl. All these complexes have been characterized by elemental analysis, magnetic measurements, electronic and infrared spectral studies. All the complexes are six-coordinate octahedral.

    • Author Affiliations

       

      K Mukkanti1 2 R P Singh1

      1. Chemistry Department, University of Delhi, Delhi - 110 007, India
      2. I & PC Division, Regional Research Laboratory, Hyderabad - 500 007, India
    • Dates

       
  • Journal of Chemical Sciences | News

© 2021-2022 Indian Academy of Sciences, Bengaluru.