• Complexes of lanthanide nitrates with N,N-diethylantipyrine-4-carboxamide

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      https://www.ias.ac.in/article/fulltext/jcsc/100/01/0001-0006

    • Keywords

       

      Lanthanide nitrate complexes; N,N-diethylantipyrine-4-carboxamide; electrolytic conductance; infrared; 13C NMR

    • Abstract

       

      New complexes of lanthanide nitrates with N, N-diethylantipyrine-4-carboxamide (DEAP), with the general formulae [Ln2(DEAP)3] [NO3]6 (where Ln = La, Pr, Nd, Sm, Tb, Ho, Er, Yb and Y) have been isolated and characterized by chemical analysis and various physical methods such as electrolytic conductance, IR and13C NMR spectral data. Electrolytic conductance values and infrared spectral studies indicate that the nitrate groups are coordinated. Infrared and13C NMR spectral analysis show that the ligand DEAP is coordinated to the tripositive metal ion through the diethylcarboxamide carbonyl and antipyrine carbonyl oxygens in a bidentate fashion.

    • Author Affiliations

       

      N Rajasekar1 S Soundararajan1

      1. Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore - 560 012, India
    • Dates

       
  • Journal of Chemical Sciences | News

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