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    • Volume change on mixing: Binary mixtures of isomeric butylamines with chloroform

      Gopal Pathak K R Patil S D Pradhan

      Physical and Theoretical Volume 98 Issue 4 May 1987 pp 319-322

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/098/04/0319-0322

    • Keywords

       

      Excess volume; butylamine; chloroform

    • Abstract

       

      The excess volume of mixing for 1-aminobutane, 2-aminobutane, 1-amino-2-methylpropane and 2-amino-2-methylpropane with chloroform were determined at 30° by the density method. TheVE were negative for all the systems and showed the following order: 2-amino-2-methylpropane>2-aminobutane>1-amino-2-methylpropane>1-aminobutane. The negativeVE were attributed to complex formation between the amine and chloroform molecules owing to H bonding, while the particular trend was attributed to the decreasing degree of self-association of amine isomers.

    • Author Affiliations

       

      Gopal Pathak1 K R Patil1 S D Pradhan1

      1. National Chemical Laboratory, Pune - 411 008, India

    • Dates

       
      Published
      May 1987
      Manuscript received
      26 May 1986
      Manuscript revised
      20 August 1986

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