• Kinetics of oxidation of ethylenediamine tetraacetic acid by aromatic N-bromamines in buffer medium

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      https://www.ias.ac.in/article/fulltext/jcsc/098/03/0213-0220

    • Keywords

       

      Bromamine-T; bromamine-B; kinetics; EDTA; acetate buffer

    • Abstract

       

      Kinetics of oxidation of disodium ethylene-diamine-tetraacetic, acid (EDTA) by bromamine-B (BAB) and bromamine-T (BAT) was investigated at 30°C in acetate buffer of pH 5. The oxidation behaviour is similar, with a first-order dependence of rate on [oxidant] and fractional orders in [EDTA] and [H+]. The influence of the reaction products, halide ions, ionic strength and dielectric constant of medium on the rate has been studied. A possible mechanism is suggested.

    • Author Affiliations

       

      K Mohan1 S Ananda1 D S Mahadevappa1

      1. Department of Chemistry, University of Mysore, Manasagangothri, Mysore - 570 006, India
    • Dates

       
  • Journal of Chemical Sciences | News

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