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    • Electrochemical reduction of some benzophenones in molten acetamide at 85°C

      R Saraswathi R Narayan

      Volume 97 Issue 3-4 October 1986 pp 403-416

    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/097/03-04/0403-0416

    • Keywords

       

      Benzophenone; molten acetamide; half-wave potentials; Hammett plot

    • Abstract

       

      Benzophenones undergo a one-step two-electron reduction in molten acetamide containing sodium acetate, both at the mercury and the glassy carbon electrodes. The reduction process is irreversible. TheE1/2 potentials of some of the benzophenones can be fitted into a Hammett plot. Theαna andkf, ho are evaluated and discussed.

    • Author Affiliations

       

      R Saraswathi1 R Narayan1

      1. Department of Chemistry, Indian Institute of Technology, Madras - 600036, India

    • Dates

       
      Published
      October 1986

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