• Oxidation of substituted phenols with metal dioxygen carrier, Co(salen) pyridinate: solvent effects

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      https://www.ias.ac.in/article/fulltext/jcsc/096/01-02/0059-0065

    • Keywords

       

      Oxidation; metal-dioxygen adduct; substituted phenols; cobalt bis(salicylaldehyde) ethylenediimine pyridinate

    • Abstract

       

      The course of the oxidation of substituted phenols with Co[bis(salicylaldehyde)ethylenediimine]pyridinate-dioxygen complex is found to be dependent on the nature of the solvents used. The various oxidation products of 2,6-dimethylphenol, 2,6-di-t-butylphenol, 2,6-di-t-butyl-4-methylphenol and hydroquinone in chloroform and methanol solvents have been isolated and characterized. Plausible intermediates leading to these reaction products are discussed.

    • Author Affiliations

       

      S Satish1 P A Ganeshpure1

      1. Research Centre, Indian Petrochemicals Corporation Limited, Vadodara - 391 346, India
    • Dates

       
  • Journal of Chemical Sciences | News

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