• Determination of stability constants from diffusion coefficient data

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/095/05-06/0517-0524

    • Keywords

       

      Stability constant; diffusion coefficient; formation function; polarography

    • Abstract

       

      Employing diffusion coefficient data evaluated by improved polarographic techniques, stability constants of Cd2+, Zn2+, Co2+ and Ni2+ with biochemical and chemical ligands using 0.1 M NaClO4 as supporting electrolyte were determined. The range ofβ values with biochemical ligands were higher than with chemical ligands. A similar trend of high and lowβ values was established using the Tanaka plot and Bjerrum’s method. Thermodynamic parameters reveal no chelate formation with either biochemical or chemical ligands.

    • Author Affiliations

       

      P N Gupta1 Anju Raina1

      1. Department of Chemistry, University of Kashmir, Srinagar - 190006, India
    • Dates

       
  • Journal of Chemical Sciences | News

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