• Correlation of x-ray photoelectron spectroscopic core level binding energies with melting point for a series of diamine dihydrochlorides

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      https://www.ias.ac.in/article/fulltext/jcsc/095/04/0397-0408

    • Keywords

       

      Diamine dihydrochloride; x-ray photoelectron spectrum; differential thermal analysis; melting point; inductive effect; hydration effect

    • Abstract

       

      X-ray photoelectron spectroscopic (XPS) and differential thermal analysis (DTA) studies of a series of diamine dihydrochlorides have shown that a linear relationship exists between the N(1 s) and Cl(2p3/2) binding energy shifts and the melting points of these salts. A theoretical model is presented to verify this empirical correlation. It is apparent that such binding energy shifts and melting points are also dependent upon intrinsic electronic and bonding features of these salts such as quaternary nitrogen substituent inductive effects, charge delocalisation within the cation, cation-anion interaction and salt hydration.

    • Author Affiliations

       

      Stephen P Roe1 John O Hill1 John Liesegang2

      1. Department of Inorganic and Analytical Chemistry, La Trobe University, Bundoora, Victoria - 3083, Australia
      2. Department of Physics and Research Centre for Electron Spectroscopy, La Trobe University, Bundoora, Victoria - 3083, Australia
    • Dates

       
  • Journal of Chemical Sciences | News

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