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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/095/03/0235-0242

    • Keywords

       

      Lanthanide perchlorates; quinoline-1-oxide; isoquinoline-2-oxide; protonnmr; electronic spectra; ir spectra; electrolytic conductance

    • Abstract

       

      Complexes of lanthanide perchlorates with quinoline-1-oxide and isoquinoline-2-oxide, have been isolated for the first time and characterised by analysis, conductance, andir,nmr and electronic spectral studies. The complexes of quinoline-1-oxide have the composition Ln(QNO)8(ClO4)3 where Ln=La, Pr or Nd and Ln(QNO)7(ClO4)3 where Ln=Gd, Dy, Ho, Er or Yb. The isoquinoline-2-oxide complexes analyse for the formula Ln(IsoQNO)7(ClO4)3 where Ln=La−Yb.

    • Author Affiliations

       

      R Kalyanasundaram1 N S Navaneetham1 S Soundararajan1

      1. Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore - 560 012, India
    • Dates

       
  • Journal of Chemical Sciences | News

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