Electron spin resonance (ESR) studies of transition metal ions in glasses have been briefly reviewed. The known relations of spin Hamiltonian parameters to structural geometries around the transition metal ion probes in glasses are summarized. RecentESR studies in glasses based on the use of Ti3+, VO2+, Mo5+, Cr3+, Fe3+, Mn2+ and Cu2+ have been emphasized. Merits ofESR in the context of structural elucidation have also been discussed.
Volume 135, 2023
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