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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/095/01-02/0159-0167

    • Keywords

       

      Ruthenium; distorsion parameters; electron spin resonance

    • Abstract

       

      Theg-tensor theory of low-spind5 configuration in octahedral fields having axial (tetragonal or trigonal) and rhombic distorsions is summarised. Illustrations taken from literature concern the following ruthenium(III) species: Ru(H2O)63+ (trigonal), Ru(bpy)33+ (trigonal), the Creutz-Taube cation (axial + rhombic) and RuCl2(HL) (L) (axial + rhombic: HL = isonitrosoketone). The rationalisation of distorsion parameters in terms of bonding is considered.

    • Author Affiliations

       

      Samaresh Bhattacharya1 Animesh Chakravorty1

      1. Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Calcutta - 700032, India
    • Dates

       
  • Journal of Chemical Sciences | News

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