• On the indirect determination ofESRg-factors byNMR of paramagnetic crystals

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      https://www.ias.ac.in/article/fulltext/jcsc/095/01-02/0129-0139

    • Keywords

       

      BroadlineNMR; paramagnetic shift tensor; g-tensor; paramagnetic resonance

    • Abstract

       

      Single crystal proton broadlineNMR of the Tutton salt K2Co(SO4)2 6H2O is reported. From the analysis of the water proton dipolar tensor proton positions have been located, based on hydrogen bonding schemes. Besides, from an analysis of the paramagnetic proton shift tensors theg-tensor of the [Co(H2O)6] chromophore has been evaluated. Comparison with directly measuredg-tensor at 4·2 K is found to be good.

    • Author Affiliations

       

      D Srinivas1 S Subramanian1

      1. Department of Chemistry, Indian Institute of Technology, Madras - 600036, India
    • Dates

       
  • Journal of Chemical Sciences | News

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