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    • Mercury(II) cyanide complexes with some bidentate ligands

      I S Ahuja

      Inorganic And Analytical Volume 93 Issue 8 December 1984 pp 1265-1271

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      https://www.ias.ac.in/article/fulltext/jcsc/093/08/1265-1271

    • Keywords

       

      ir spectra; mercury(II) cyanide; stereochemistry; coordination compounds; bidentate ligands

    • Abstract

       

      Coordination compounds formed by the interaction of mercury(II) cyanide with some bidentate ligands—ethylenediamine, N,N-diethylethylenediamine, 1,3-propanediamine, 1,5-pentanediamine, 2,2′-bipyridylamine, 1,4-dioxane, morpholine, methylpyrazine, 4,4′-bipyridyl and 4,4′-bipyridyl N,N′-dioxide—have been prepared. Stoichiometries of the complexes have been established by metal, carbon and nitrogen estimations. The complexes isolated in the solid state have been characterized byir spectroscopy down to 200 cm−1 to elucidate the metal-ligand and metal-cyanide bonding modes. Tentative stereochemistries of the complexes in the solid state are discussed.

    • Author Affiliations

       

      I S Ahuja1

      1. Chemistry Department, Banaras Hindu University, Varanasi - 221 005, India

    • Dates

       
      Published
      December 1984
      Manuscript received
      20 September 1983
      Manuscript revised
      17 January 1984

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