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      https://www.ias.ac.in/article/fulltext/jcsc/093/05/0843-0848

    • Keywords

       

      Phosphate coordination; copper(II) phosphate complexes; spectral studies; cis-distorted octahedral complexes

    • Abstract

       

      The structural aspects of phosphate coordination in Cu(bipy)2 (H2PO4)2∼0·25 H3PO4 (1) and Cu(phen)2(H2PO4)2∼0·25 H3PO4 (2) (bipy=2,2′ bipyridyl; phen=1,10 phenanthroline) have been investigated byir, electronic andesr spectra. In both complexes bidentate coordination from H2PO4− ion is suggested. The complexes have been assignedcis-distorted octahedral stereochemistry. It is interesting that the stereochemistry is essentially of a static nature in (1) while it is fluxional in (2).

    • Author Affiliations

       

      M S Sastry1 T kesavadas1 G S Rao1 M D Sastry2

      1. Chemistry Division, Bhabha Atomic Research Centre, Bombay - 400 085, India
      2. Radiochemistry Division, Bhabha Atomic Research Centre, Bombay - 400 085, India

    • Dates

       
      Published
      June 1984
      Manuscript received
      22 July 1983
      Manuscript revised
      16 November 1983

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