• Binuclear and polynuclear complexes of rhodium with nitrogen heterocycles as bridging ligands

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      https://www.ias.ac.in/article/fulltext/jcsc/093/04/0753-0766

    • Keywords

       

      Binuclear complexes; polynuclear complexes; rhodium; nitrogen heterocycles; bridging ligands

    • Abstract

       

      A number of binuclear and polynuclear complexes of rhodium(I) with bridging nitrogen heterocycles are known. X-ray crystal structure analysis of some of the complexes has established the bridging nature of the heterocycles. The proximity of the metal atoms is found to considerably influence the electronic spectra of the complexes. Oxidative addition reactions of these compounds are yet to be properly investigated. Some of these compounds are efficient hydrogenation and hydroformylation catalysts.

    • Author Affiliations

       

      N M N Gowda1 R Halesha1 G K N Reddy1

      1. Department of Chemistry, Central College, Bangalore University, Bangalore - 560001, India
    • Dates

       
  • Journal of Chemical Sciences | News

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      Posted on July 25, 2019

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