• Reactions of dichloro-bis(cyclopentadienyl)titanium(IV) with bidentate Schiff bases

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    • Keywords


      Cyclopentadienyl; titanium(IV); Schiff bases

    • Abstract


      A series of Cp2Ti(SB)Cl complexes, whereSB is the anion of bidentate Schiff bases derived from salicylaldehyde and different primary aminesviz o-anisidine,m-anisidine,o-phenetidine,o-chloroaniline,m-chloroaniline,m-nitroaniline, α-naphthylamine and benzylamine, have been synthesised by the reaction of dichloro-bis(cyclopentadienyl) titanium(IV), Cp2TiCl2, and bidentate Schiff base (sbh) in a 1:1 molar ratio in refluxingthf in the presence of triethylamine. The new derivatives have been characterised on the basis of their elemental analyses, conductance measurements and spectral (IR,1Hnmr and electronic) studies

    • Author Affiliations


      B Khera1 N K Kaushik1

      1. Department of Chemistry, University of Delhi, Delhi - 110 007, India
    • Dates

  • Journal of Chemical Sciences | News

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