• Synthesis and characterization of hexa, hepta and octa-coordinated Nb(V) complexes of N,N’-(bdsubstituted)-formamidino-N’-(substituted) carbamides and thiocarbamides

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      https://www.ias.ac.in/article/fulltext/jcsc/092/06/0605-0612

    • Keywords

       

      Nb(V) naphthoxides; niobium pentachloride; carbamides; thiocarbamides

    • Abstract

       

      The non-electrolytic compounds of composition MCln(ONp)5-n have been prepared by digesting the niobium pentachloride with β-naphthol in an appropriate molar ratio in carbon tetrachloride. The hexa-, hepta- and octa-coordinated derivatives of Nb(V) have been isolated by reacting Nb (ONp)5 with N,N’-diarylformamidino-N“-arylcarbamides, thiocarbamides and N-benzoylformamidino-N’-arylcarbamides and thiocarbamides, of the general formula Nb (ONp)4(L); Nb (ONp)3(L)2 and Nb (ONp)2(L)3; (L= a molecule of bidentate ligand).

    • Author Affiliations

       

      K L Madhok1 2

      1. Centre for R D and A T, Indian Institute of Technology, Hauz Khas, New Delhi - 110016, India
      2. School of Studies in Chemistry, Jiwaji University, Gwalior - 474011, India
    • Dates

       
  • Journal of Chemical Sciences | News

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