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    • Stereochemistry of copper (II), nickel (II) and cobalt (II) 2′-hydroxy-5′-X-chalconeoxime complexes

      C Natarajan M Palaniandavar

      Inorganic and Analytical Volume 92 Issue 3 June 1983 pp 265-270

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/092/03/0265-0270

    • Keywords

       

      Chalconeoxime complexes; high spin; ligand field spectra

    • Abstract

       

      Cu (II), Ni (II) and Co (II) complexes of the type ML2,2B where L = 2′-hydroxy-5′-X-chalconeoxime (X = H, CH3, Cl) and B = water or pyridine have been obtained from chalconeoximes and by reacting the preformed metal (II) chalcone complexes with hydroxylamine. They have been characterised on the basis of elemental and thermal analyses, conductivity and magnetic measurements and ligand field and m spectra. All the complexes are high-spin octahedral species in contrast to the low-spin square planar Ni (II) and Co (II) salicylaldoxime complexes. IR spectral studies indicate that conjugation is relatively damped in chalconeoxime. The lower ligand field strangth of the oxime is attributed to the weak M-N bonding and less extensive dπ— π*3 back-bonding. Replacement of water by pyridine weakens metal-oximino bond in the complexes.

    • Author Affiliations

       

      C Natarajan1 2 M Palaniandavar1 2

      1. Department of Inorganic Chemistry, Madurai Kamaraj University, Madurai - 625 021, India
      2. Madurai Kamaraj University Extension Centre, St. John’s College campus, Palayamkottai - 627 002, India

    • Dates

       
      Published
      June 1983
      Manuscript received
      12 August 1982
      Manuscript revised
      28 December 1982

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