• Reactions of silylated Schiff bases with organotitanium(IV) and organotin(IV) chlorides

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    • Keywords


      Organometallic reactions; silylated Schiff bases; organotitanium; organotin

    • Abstract


      The interactions of silylated dibasic quadridentate Schiff bases derived fromo-hydroxyacetophenone and ethylenediamine and orthophenylenediamine with (π-C5H5)TiCl3, (π-C5H5)(MeO)TiCl2, (MeO)2TiCl2, Me2SnCl2 and MeSnCl3 yield a new series of organotitanium(IV) and tin(IV) compounds. The reactivity of (π- C5H5)Ti(L1)Cl and MeSn(L1)Cl, towards MeSH, Me2NSiMe3, SiMe3N3 and Me3SiC = CPh are also described. The structures for the compounds isolated are proposed on the basis of elemental analyses, molecular weights, IR and1H nmr spectroscopic studies.

    • Author Affiliations


      K Dey1 S Ray1 D Koner1

      1. Department of Chemistry, University of Kalyani, Kalyani - 741 235, India
    • Dates

  • Journal of Chemical Sciences | News

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