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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/091/04/0347-0350

    • Keywords

       

      Solvent extraction; synergism; U(TTA)4; neutral donor adducts

    • Abstract

       

      Adduct formation between U(TTA)4 and neutral organosulphoxide donors dibenzyl sulphoxide (dbso), dimethyl sulphoxide (dmso), dihexyl sulphoxide (dhso) and dioctylsulphoxide (doso) was studied by spectrophotometry. Each of these donors form a 1 : 1 adduct with U(TTA)4. The adduct formation constants (log βAB) were calculated from spectral changes and were found to be 3.10 (dbso), 3.23 (dmso), 3.62 (dhso) and 3.64 (doso).

    • Author Affiliations

       

      A Ramanujam1 N M Gudi1 M N Nadkarni1 S K Patil1 2 V V Ramakrishna1 2

      1. Fuel Reprocessing Division, Bhabha Atomic Research Centre, Bombay - 400 085, India
      2. Radiochemistry Division, Bhabha Atomic Research Centre, Bombay - 400 085, India
    • Dates

       
  • Journal of Chemical Sciences | News

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