Synthesis of some zerovalent complexes of ironvia aryldiazenato cationic complexes
Bis (triphenylphosphine) dicarbonylaryldiazenato-iron, [Fe0 (ArN2) (CO)2 (PPhs)2]+(I), reacts in a solution of LiOEt under nitrogen atmosphere, with a variety of group V donor ligands, substituting the aryldiazenato ligand, ArN2+. The effect of substitution on the stretching frequency of CO is discussed.
Volume 134, 2022
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