• Synthesis of some zerovalent complexes of ironvia aryldiazenato cationic complexes

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      https://www.ias.ac.in/article/fulltext/jcsc/091/04/0343-0346

    • Keywords

       

      Aryldiazenato cationic complex; substitution reactions; zero-valent complexes; iron

    • Abstract

       

      Bis (triphenylphosphine) dicarbonylaryldiazenato-iron, [Fe0 (ArN2) (CO)2 (PPhs)2]+(I), reacts in a solution of LiOEt under nitrogen atmosphere, with a variety of group V donor ligands, substituting the aryldiazenato ligand, ArN2+. The effect of substitution on the stretching frequency of CO is discussed.

    • Author Affiliations

       

      S Vancheesan1

      1. Department of Chemistry, Indian Institute of Technology, Madras - 600 036, India
    • Dates

       
  • Journal of Chemical Sciences | News

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