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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/091/03/0261-0266

    • Keywords

       

      MnO; FeO; magnetic susceptibility

    • Abstract

       

      Magnetic susceptibility studies of Mn1-xMxO (M = Zn, x≤0.1; M = Mg, x≤0.12;M = Fe, x≤0.4) in the range 77 to 300 K are reported. The methods of preparation of Mn1-xMxO systems preclude the presence of trivalent ions. The M1-xFexO system shows anomalous behaviour aroundx = 0.2–0.3. The results are discussed in terms of competition between the nearest neighbour and the next-near-neighbour interactions, dilution effects and cooperative effects of FeO6 octahedra.

    • Author Affiliations

       

      C E Deshpande1 P P Bakare1 M N S Murthy1 N Y Vasanthacharya1 2 P Ganguly1 2

      1. National Chemical Laboratory, Pune - 411 008, India
      2. Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore - 560012, India

    • Dates

       
      Published
      June 1982
      Manuscript revised
      21 April 1982

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