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    • Reactions of co-ordinated ligands: Kinetics and mechanisms in the charge transfer interaction between dichloro or diaquo triethylene tetramine Co(III) and ferrocyanide

      G Visalakshi K S Venkateswarlu

      Physical and Theoretical Volume 91 Issue 3 June 1982 pp 213-221

    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/091/03/0213-0221

    • Keywords

       

      Cis-a diaquo Co (III) triethylene tetramine; charge transfer IT transition; kinetics of formation

    • Abstract

       

      The cherry red-coloured solid state product obtained by the reaction ofcis-σ diaquo Co (III) triethylene tetramine with ferrocyanide was examined by thermogravimetric, infrared and Mössbauer techniques. Its electronic spectrum in aqueous medium was interpreted to consist of charge transfer IT transition at 440 nm and a ligand field transition around 330 nm. The kinetics of formation of this 1:1 product in solution was also studied.

    • Author Affiliations

       

      G Visalakshi1 K S Venkateswarlu1

      1. Reactor Chemistry Section, Chemcal group, Bhabha Atomic Research Centre, Bombay - 400085, India

    • Dates

       
      Published
      June 1982
      Manuscript received
      8 November 1980
      Manuscript revised
      7 April 1982

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