• Complexes of Cu(II), Ni(II) and Co(II) with isophthalic dihydrazide

    • Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/091/01/0001-0006

    • Keywords

       

      Isophthalic dihydrazide; metal chloride complexes; metal sulphate complexes

    • Abstract

       

      Complexes of isophthalic dihydrazide (IPZ) of the type MCl2(IPZ)·H2O [M=Cu(II), Ni(II), Co(II)] and MSO4(IPZ)·H2O [M=Cu(II), Ni(II)] have been prepared and characterised from elemental analysis, magnetic moment, visible, IR, and ESR spectra. Based on these data a polymeric octahedral structure has been assigned to MCl2(IPZ)·H2O complexes and sulphate bridged four coordinate polymeric structure for MSO4(IPZ)·H2O complexes. Thermogravimetric studies of these complexes show that the thermal stability decreases in the order Ni(II)> Co(II)>Cu(II).

    • Author Affiliations

       

      C G Kumbhar1

      1. Institute of Armament Technology, Girinagar, Pune - 411 025, India
    • Dates

       
  • Journal of Chemical Sciences | News

© 2021-2022 Indian Academy of Sciences, Bengaluru.