• Metal derivatives of organoantimony compounds: reactions of anhydrous Zr(IV), Nb(V) and W(VI) chlorides with arylantimony compounds

    • Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/090/06/0555-0558

    • Keywords

       

      Stibonium-metal chloride complexes

    • Abstract

       

      The reactions of anhydrous Zr(IV), Nb(V) and W(VI) chloride with tetraphenylstibonium chloride and triphenylantimony dichloride have been studeid. Tetraphenylstibonium chloride was found to form ionic complexes with the anhydrous chlorides of metals whereas triphenylantimony dichloride formed adducts involving chlorine bridges. The complexes have been characterized by elemental analyses, IR spectra, conductivity and magnetic susceptibility measurements. Only tungsten(V) chloride was reduced when reacted with triphenylstibine.

    • Author Affiliations

       

      Hemant K Sharma1 S N Dubey1 D M Puri1

      1. Department of Chemistry, Kurukshetra University, Kurukshetra - 132119, India
    • Dates

       
  • Journal of Chemical Sciences | News

© 2021-2022 Indian Academy of Sciences, Bengaluru.