• Spectral studies of the newly synthesized azomethine derivatives of zirconium(IV)

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/090/05/0461-0465

    • Keywords

       

      Zirconium (IV) complexes; azomethine derivatives; Schiff bases; spectral studies; UV spectra

    • Abstract

       

      Equimolar and bimolar reactions of zirconium isopropoxide with bibasic tridentate azomethine (AZH2) having the donor system ONO have been carried out and derivatives of the type Zr(OPr1)2(AZ) and Zr(AZ)2 [Where AZ2− is the anion of the azomethine molecule] have been isolated. The labile nature of the isopropoxy groups in 1∶1 derivatives has been shown by carrying out exchange reactions with equimolar amount of 2-methylpentane-2,4-diol. All the newly synthesized derivatives have been characterized on the basis of elemental analysis, conductance measurements, molecular weight determinations and infrared, ultraviolet, visible and proton magnetic resonance spectral studies.

    • Author Affiliations

       

      R K Sharma1 R V Singh1 J P Tandon1

      1. Department of Chemistry, University of Rajasthan, Jaipur - 302 004, India
    • Dates

       
  • Journal of Chemical Sciences | News

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