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    • Phosphorus chloride-metal chloride-alkyl chloride complexes: Reactions with vanadium(III) chloride and vanadium(V) oxychloride

      Sneh Lata Soran Singh S N Dubey D M Puri

      Inorganic and Analytical Volume 90 Issue 4 August 1981 pp 333-337

    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/090/04/0333-0337

    • Keywords

       

      Organophosphonium; polychloro metallates; vanadium

    • Abstract

       

      The reactions of anhydrous vanadium(III) chloride and vanadium(V) oxychloride with trichloro- and phenyl dichloro-phosphine have been studied in the presence of alkylating agents such astert-butyl chloride,tert-amyl chloride, cyclohexyl chloride and triphenyl methyl chloride. Solid products have been obtained. The structures of the complexes have been assigned on the basis of elemental analyses, infrared spectra, magnetic susceptibility and conductivity data.

    • Author Affiliations

       

      Sneh Lata1 Soran Singh1 S N Dubey1 D M Puri1

      1. Department of Chemistry, Kurukshetra University, Kurukshetra - 132 119, India

    • Dates

       
      Published
      August 1981
      Manuscript received
      21 March 1981
      Manuscript revised
      19 May 1981

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