• Phosphorus chloride-metal chloride-alkyl chloride complexes: Reactions with vanadium(III) chloride and vanadium(V) oxychloride

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/090/04/0333-0337

    • Keywords

       

      Organophosphonium; polychloro metallates; vanadium

    • Abstract

       

      The reactions of anhydrous vanadium(III) chloride and vanadium(V) oxychloride with trichloro- and phenyl dichloro-phosphine have been studied in the presence of alkylating agents such astert-butyl chloride,tert-amyl chloride, cyclohexyl chloride and triphenyl methyl chloride. Solid products have been obtained. The structures of the complexes have been assigned on the basis of elemental analyses, infrared spectra, magnetic susceptibility and conductivity data.

    • Author Affiliations

       

      Sneh Lata1 Soran Singh1 S N Dubey1 D M Puri1

      1. Department of Chemistry, Kurukshetra University, Kurukshetra - 132 119, India
    • Dates

       
  • Journal of Chemical Sciences | News

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