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    • Polarography of europium(III) in water-dimethylformamide mixtures

      V R Chandrasekaran A K Sundaram

      Physical and Theoretical Volume 90 Issue 4 August 1981 pp 275-280

    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/090/04/0275-0280

    • Keywords

       

      Polarography; europium; dimethylformamide

    • Abstract

       

      The kinetics of the electrochemical reduction of europium(III) in water-N, N dimethyl formamide mixtures in potassium chloride medium has been studied. The formal rate constant for the reduction increases markedly from 10−4 cm sec−1 in low concentrations to 10−2 cm sec−1 at high concentrations of the solvent. The effects of solvent on the formal potential and diffusion current are discussed.

    • Author Affiliations

       

      V R Chandrasekaran1 A K Sundaram1

      1. Analytical Chemistry Division, Bhabha Atomic Research Centre, Trombay, Bombay - 400 085, India

    • Dates

       
      Published
      August 1981
      Manuscript received
      24 November 1980

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