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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/089/05/0435-0439

    • Keywords

       

      Vilsmeier reaction; 1- and 2-tetralones; chlorobisformylnaphthalenes; synthesis and mechanism

    • Abstract

       

      Vilsmeier reaction on a few representative 6- and 7-methoxy-1- and 2-tetralones has been investigated. While 1-tetralones give the corresponding 1-chloro-2-formyl-3,4-dihydronaphthalenes, the 2-tetralones afford 1,3-bisformyl-2-chloronaphthalenes. Spectral characteristics of all the products obtained are given and a mechanistic proposal has been made to explain the observed chlorobisformylation.

    • Author Affiliations

       

      P Anantha Reddy1 G S Krishna Rao1

      1. Department of Organic Chemistry, Indian Institute of Science, Bangalore - 560 012, India
    • Dates

       
  • Journal of Chemical Sciences | News

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