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    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/089/03/0301-0307

    • Keywords

       

      Fries reaction; beta-naphthyl cinnamate; dearylative cyclization; 9-hydroxy-phenalen-l-one; aluminum chloride

    • Abstract

       

      Reaction of β-naphthyl cinnamate with anhydrous aluminum chloride afforded 9-hydroxyphenalenone5 by a Fries rearrangement followed bya dearylative cyclisation. 9-Hydroxy-3-phenyl-2,3-dihydrophenaIen-l-one7 was identified as an intermediate.

    • Author Affiliations

       

      T Manimaran1 T Jayachandran1 V T Ramakrishnan1 2

      1. Department of Organic Chemistry, University of Madras, Madras - 600 025, India
      2. Department of Chemistry, University of Illinois, Chicago Circle, Illinois - 60680, USA

    • Dates

       
      Published
      June 1980
      Manuscript received
      19 September 1979
      Manuscript revised
      24 April 1980

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