• Mechanism of formation of Cu(II) carboxylates in the solid state 1. Kinetics of reactions between benzoic acid, salicylic acid and CuCO3 Cu(OH)2

    • Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/089/02/0125-0130

    • Keywords

       

      Benzoic acid; salicylic acid; copper carbonate; solid state reactions; kinetics

    • Abstract

       

      The kinetic data for reactions between aromatic acids, i.e. benzoic acid, salicylic acid and basic copper carbonate in the solid state have been recorded. The measurements have been made at various temperatures for fixed sizes of the particles at constant compression. The products are characterised by infrared and reflectance spectra. The reactions are diffusion-controlled with activation energy of 71.8 and 115.0±5 kJ mol−1 for the formation of Cu(II) benzoate and Cu(II) salicylate respectively.

    • Author Affiliations

       

      P S Bassi1 B R Gupta1 I B Sharma1

      1. Department of Chemistry, University of Jammu, Jammu - 180 001, India
    • Dates

       
  • Journal of Chemical Sciences | News

© 2021-2022 Indian Academy of Sciences, Bengaluru.