• Spectrophotometric study of the formation of adducts between U(TTA)4 and some neutral donors

    • Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/088/04/0303-0312

    • Keywords

       

      Solvent extraction; synergism; U(TTA)4-neutral donor adducts; coordination

    • Abstract

       

      Adduct formation between U(TTA)4 and neutral donors triphenyl phosphine oxide (TPPO), tri-n-butyl phosphate (TBP) and methyl-isobutyl ketone (MIBK) in benzene was studied by absorption spectra. All the three donors form 1∶1 adduct with U(TTA)4. The adduct formation constants calculated from the spectral changes were 5·2×104, 1·1×103 and ∼0·8 for the adducts with TPPO, TBP and MIBK respectively. The adduct formation apparently increases the coordination number of U(IV) from 8, in the U(TTA)4 to 9 in the adduct formed.

    • Author Affiliations

       

      S K Patil1 V V Ramakrishna1 A Ramanujam1

      1. Radiochemistry Division, Bhabha Atomic Research Centre, Bombay - 400 085
    • Dates

       
  • Journal of Chemical Sciences | News

© 2021-2022 Indian Academy of Sciences, Bengaluru.