• Volume change on mixing of isomeric butanols with normal heptane

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/088/04/0249-0255

    • Keywords

       

      Volume change; excess volumes; binary systems; butanols-heptane

    • Abstract

       

      Volume changes on mixing of isomeric butanols withn-heptane have been determined at 25°C and that of tertbutanol at 26°C. All the four systems show a positive excess volume throughout concentration range. The excess volumes have been found to vary in the order of tert >sec >iso >n-butanols. The order of the excess volume has been attributed to breaking of hydrogen bonds of associated species of alcohol by dilution withn-heptane and more random distribution ofn-heptane molecules.

    • Author Affiliations

       

      Anil Kumar1 S D Pradhan1 S S Katti1

      1. National Chemical Laboratory, Poona - 411 008
    • Dates

       
  • Journal of Chemical Sciences | News

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