• 2,4-Lutidine-1-oxide complexes of lanthanide perchlorates

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      https://www.ias.ac.in/article/fulltext/jcsc/088/02/0131-0135

    • Keywords

       

      Lanthanide perchlorates; 2,4-Lutidine-1-oxide; hypersensitive bands

    • Abstract

       

      2,4-Lutidine-1-oxide (2,4-LutO) complexes of lanthanide perchlorates of the formulae Ln2(2,4-LutO)13(ClO4)6 (Ln = Pr and Nd) and Ln2(2,4-LutO)15 (ClO4)6 (Ln = La, Tb, Dy, Ho and Yb) have been prepared and characterised by chemical analysis, IR, NMR, conductance and electronic spectral data. Proton NMR data along with the IR data show that the ligand coordinates to the metal ion through the oxygen. Conductance data of the complexes in acetone and nitrobenzene indicate that the perchlorate is not coordinated to the metal ion.

    • Author Affiliations

       

      N S Navaneetham1 S Soundararajan1

      1. Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore - 560 012
    • Dates

       
  • Journal of Chemical Sciences | News

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