• Electrochemical reduction of Cu(II)-EDTA complex at dropping mercury electrode. An impedance approach

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/088/01/0033-0041

    • Keywords

       

      Electrochemical reduction; Cu-EDTA system; impedance method; complex plane polarography

    • Abstract

       

      The study of electrochemical reduction of Cu(II)-EDTA system by phase sensitive a.c. impedance method at dropping mercury electrode reveals several interesting features. The complex plane polarograms exhibit loop like shape in contrast to the classical zinc ion reduction where crest like shape is found. Again, the relative placement of peaks of in-phase and quadrature components, and the relative placement of portions before and after the peaks of complex plane polarograms are different from that of zinc ion reduction. The complex plane plots suggest that electrochemical reduction of Cu-EDTA is charge transfer controlled.

    • Author Affiliations

       

      G A Bhat1

      1. Department of Organic Chemistry, Indian Institute of Science, Bangalore - 560 012
    • Dates

       
  • Journal of Chemical Sciences | News

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