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    • Polarographic study of the kinetics of oxidation of allyl alcohol by chloramine-T

      K Ganapathy B Vijayan

      Physical and Theoretical Volume 87 Issue 6 June 1978 pp 215-217

    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/087/06/0215-0217

    • Keywords

       

      Kinetics; allyl alcohol; chloramine-T; polarographic method

    • Abstract

       

      The kinetics of oxidation of allyl alcohol by chloramine-T (CAT) in presence of 0·02 M hydrochloric acid and at a constant ionic strength (μ=0·5 M) have been studied polarographically at six different temperatures between 30°C and 45°C. The reaction shows first order dependence on concentration of chloramine-T. The energy and entropy of activation have been found to be 13·7 kcal mol−1 and −28·4 e.u. respectively.

    • Author Affiliations

       

      K Ganapathy1 B Vijayan1

      1. Department of Chemistry, Annamalai University, Annamalainagar - 608 101

    • Dates

       
      Published
      June 1978
      Manuscript received
      4 April 1977
      Manuscript revised
      18 March 1978

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