1. Home
    2. Journals
    3. Journal of Chemical Sciences
    4. Volume 87
    5. Issue 4

    • Studies on alkoxy complexes of alkyltin (IV) in non-aqueous solvents

      R C Mehrotra A K Rai N C Jain

      Inorganic and Analytical Volume 87 Issue 4 April 1978 pp 61-67

    • Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/087/04/0061-0067

    • Keywords

       

      Alkyltin (IV) species; alkoxy complexes; non-aqueous solvents

    • Abstract

       

      Visual, conducto- and potentiometric titrations of mono-, di- and tri- alkyltin (IV) chlorides with alkali metal alkoxides have been carried out in anhydrous non-aqueous solvents. Evidence for the formation of a number of species of the type M[(R′Sn)2(OR)7], R′nSn(OR)4−n and [(R′Sn)2(OR)3]Cl3 (where M=Na or K; R′=Me, Et or Bu; R=Me, Et or Pri; n=1, 2 or 3) has been obtained. Di- and tri- alkyltin (IV) moieties appear to have a negligible tendency to form double alkoxides with alkali metals.

    • Author Affiliations

       

      R C Mehrotra1 A K Rai1 2 N C Jain1

      1. Chemical Laboratories, University of Delhi, Delhi - 110 007
      2. Department of Chemistry, University of Rajasthan, Jaipur - 302 004

    • Dates

       
      Published
      April 1978
      Manuscript received
      23 August 1977
      Manuscript revised
      20 January 1978

  • Journal of Chemical Sciences | News

© 2023-2024 Indian Academy of Sciences, Bengaluru.

Contact | Site index