• Studies on alkoxy complexes of alkyltin (IV) in non-aqueous solvents

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      https://www.ias.ac.in/article/fulltext/jcsc/087/04/0061-0067

    • Keywords

       

      Alkyltin (IV) species; alkoxy complexes; non-aqueous solvents

    • Abstract

       

      Visual, conducto- and potentiometric titrations of mono-, di- and tri- alkyltin (IV) chlorides with alkali metal alkoxides have been carried out in anhydrous non-aqueous solvents. Evidence for the formation of a number of species of the type M[(R′Sn)2(OR)7], R′nSn(OR)4−n and [(R′Sn)2(OR)3]Cl3 (where M=Na or K; R′=Me, Et or Bu; R=Me, Et or Pri; n=1, 2 or 3) has been obtained. Di- and tri- alkyltin (IV) moieties appear to have a negligible tendency to form double alkoxides with alkali metals.

    • Author Affiliations

       

      R C Mehrotra1 A K Rai1 2 N C Jain1

      1. Chemical Laboratories, University of Delhi, Delhi - 110 007
      2. Department of Chemistry, University of Rajasthan, Jaipur - 302 004
    • Dates

       
  • Journal of Chemical Sciences | News

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