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      Permanent link:
      https://www.ias.ac.in/article/fulltext/boms/045/0235

    • Keywords

       

      Phthalocyanine; synthesis; fluorescence; singlet oxygen; nonlinear optic.

    • Abstract

       

      In this study, firstly, 4-(2-(benzhydryloxy)phenoxy)phthalonitrile compound was synthesized. Then, a new 2, 10, 16, 24–tetrakis (2-(benzhydryloxy) phenoxy phthalocyaninato) zinc (II) complex was synthesized. The characterization of the obtained structure was investigated using spectroscopy techniques, including mass, nuclear magnetic resonance, infrared, electronic absorption spectroscopies. The nonlinear optical properties were investigated by virtue of femtosecond laser z-scan method. The aggregation–concentration relationship of zinc phthalocyanine compound, the photophysical and photochemical properties was dealt by UV–Vis spectroscopy and spectrofluorophotometer. In addition,the calculated values of the nonlinear absorption coefficient, ${\beta}$ (${\sim}$10$^{–10}$ cm W$^{–1}$), the nonlinear refraction index, $n_2$ (${\sim}$10$^{–16}$ cm$^2$ W$^{–1}$) and third-order susceptibilities, ${\chi}^{(3)}$ (${\sim}$10$^{–11}$ esu) for 2, 10, 16, 24–tetrakis (2-(benzhydryloxy)phenoxy phthalocyaninato) zinc (II) have been seen to be in line with literature.

    • Author Affiliations

       

      D GÜNGÖRDÜ SOLĞUN1 Y GÜNDOĞDU2 3 H Ş KILIÇ3 4 5 M S AĞIRTAŞ1

      1. Faculty of Science, Department of Chemistry, Van Yuzuncu Yıl University, 65080 Van, Turkey
      2. Department of Computer Technologies, Kadınhanı Faik İçil Vocational High School, University of Selçuk, 42800 Konya, Turkey
      3. Directorate of Laser Induced Proton Therapy Application and Research Center, University of Selçuk, 42031 Konya, Turkey
      4. Faculty of Science, Department of Physics, University of Selçuk, 42031 Konya, Turkey
      5. Directorate of High Technology Research and Application Center, University of Selçuk, 42031 Konya, Turkey

    • Dates

       
      Published
      24 November 2022
      Manuscript received
      22 January 2022
      Accepted
      29 July 2022
      Final version published online
      24 November 2022

    • Supplementary Material

       

  • Bulletin of Materials Science | News

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    • Editorial Note on Continuous Article Publication

      Posted on July 25, 2019

      Click here for Editorial Note on CAP Mode

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