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      https://www.ias.ac.in/article/fulltext/boms/045/0175

    • Keywords

       

      Firework; free-standing film; magnesium boride (MgB$_2$); sodium nitrite (NaNO$_2$); poly(vinyl alcohol) (PVA).

    • Abstract

       

      We have demonstrated a simple fabrication methodology of free-standing polymer composite film firework that sparkles, provides colour display and moderate sound, yet is less polluting. The polymer composite film fireworks arecomposed of magnesium boride (MgB$_2$), sodium nitrite (NaNO$_2$) and poly(vinyl alcohol) (PVA). This study also suggested that a flammable, explosive powder composition can be made of two very common inorganic precursors, mainly NaNO$_2$ and MgB$_2$. This is the first report demonstrating composite film fireworks with new flammable composition using metal boride as a primary precursor, which can also be used in conventional fireworks fabrication, replacing the traditional fuel, mainly gunpowder. The film fireworks were free from charcoal, sulphur, metal powder and paper. Therefore, they substantially lower the odour and CO$_x$, NO$_x$ emissions and minimize the substantial trash generated when burned. Most importantly, film firework‘s minimum ignition temperature and exothermic decomposition temperature are much higher than the ambient temperature; hence are safe to handle.

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    • Author Affiliations

       

      VIJAYAKRISHNAN JEYAVANI1 2 RAJENDRA KUMAR3 2 PATTAYIL ALIAS JOY1 2 SHATABDI POREL MUKHERJEE1 2

      1. Physical and Materials Chemistry Division, CSIR-National Chemical Laboratory, Pune 411008, India
      2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India
      3. Chemical Engineering and Process Development, CSIR-National Chemical Laboratory, Pune 411008, India
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    • Supplementary Material

       
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